Dimethyl(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)zinc(II)
نویسندگان
چکیده
The title compound, [Zn(CH(3))(2)(C(15)H(11)N(3))], was synthesized by the addition of dimethyl-zinc to 2,2':6',2''-terpyridine and was crystallized by the slow evaporation of THF. The penta-coordinate Zn(II) atom, lying on a twofold rotation axis, displays a distorted trigonal-bipyramidal geometry, with two terminal N atoms at the axial positions and the central N atom and two methyl C atoms at the equatorial positions.
منابع مشابه
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ2 O:O′]
In the title compound, [Zn(C(14)H(8)O(5))(C(15)H(11)N(3))](n), both the Zn(II) ion and the oxydibenzoate ligand are located on a twofold rotation axis. The Zn(II) centre is coordinated by three N atoms from a chelating 2,2':6',2''-terpyridine ligand and two O atoms from two 2,2'-oxydibenzoate ligands, forming a distorted trigonal-bipyramidal coordination environment. Further coordination via th...
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